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Graphite Composite Material Design Guide
The purpose of this design guide is to provide general
information on graphite (carbon fiber) composite materials
and some guidelines for designing lightweight high performance
products with graphite composites. If you have more specific
questions, please contact our engineers at Performance Composites,
and they will gladly assist you.
Graphite (Carbon Fiber) Composite Materials (Definition
and History)
Composite materials are made by combining reinforcement
(fiber) with matrix (resin), and this combination of the
fiber and matrix provide characteristics superior to either
of the materials alone. In a composite material, the fibers
carry majority of the loads, and are the major factor in
the material properties. The resin helps to transfer load
between fibers, prevents the fibers from buckling, and binds
the materials together.
Graphite composites have exceptional mechanical properties
which are unequaled by other materials. The material is
strong, stiff, and lightweight. Graphite composite is the
material of choice for applications where lightweight &
superior performance is paramount, such as components for
spacecrafts, fighter aircrafts, and racecars.
Graphite fibers (sometimes called carbon fibers) are made
from organic polymer such as polyacrylonitrile. The material
is drawn into fibers and kept under tension while it is
heated under high temperature (> 1000C). 2 dimensional carbon-carbon
crystals (graphite) are formed when the hydrogen is driven
out. The carbon-carbon chain has extremely strong molecular
bonds (diamond is a 3 dimensional carbon-carbon crystal),
and that is what gives the fibers its superior mechanical
properties.
Historically, graphite composites have been very expensive,
which limited its use to only special applications. However,
over the past fifteen years, as the volume of graphite fiber
consumption has increased and the manufacturing processes
have improved, the price of graphite composites has steadily
declined. Today graphite composites are economically viable
in many applications such as sporting goods, performance
boats, performance vehicles, and high performance industrial
machinery.
Applications of Graphite Composite Materials
Composite materials are extremely versatile. The engineer
can choose from a wide variety of fibers and resins to obtain
the desired material properties. Also the material thickness
and fiber orientations can be optimized for each application.
The three greatest advantages of graphite composites are:
- High specific stiffness (stiffness divided by density)
- High specific strength (strength divided by density)
- Extremely low coefficient of thermal expansion (CTE)
Please
see table 1 for a comparison of costs and mechanical properties
of graphite composite, fiberglass composite, aluminum, and
steel. Due to the wide variety of graphite fibers and resins
available, and the numerous combinations of the materials,
the properties are listed in ranges.
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TABLE 1
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Graphite Composite (aerospace grade)
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Graphite Composite (commercial grade)
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Fiberglass Composite
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Aluminum 6061 T-6
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Steel, Mild
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|
Cost $/LB
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$20-$250+
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$5-$20
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$1.50-$3.00
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$3
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$.30
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Strength (psi)
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90,000-200,000
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50,000-90,000
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20,000-35,000
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35,000
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60,000
|
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Stiffness (psi)
|
10 x 106 - 50 x 106
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8 x 106 - 10 x 106
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1 x 106 - 1.5 x 106
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10 x 106
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30 x 106
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Density (lb/in3)
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.050
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.050
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.055
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.10
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.30
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| Specific Strength |
1.8 x 106 - 4 x 106
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1 x 106 -
1.8 x 106
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363,640 - 636,360
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350,000
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200,000
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| Specific Stiffness |
200 x 106 -
1,000 x 106
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160 x 106 -
200 x 106
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18 x 106 -
27 x 106
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100 x 106
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100 x 106
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| CTE (in/in-F) |
-1 x 10-6 -
1 x 10-6
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1 x 10-6 -
2 x 10-6
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6 x 10-6 -
8 x 10-6
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13 x 10-6
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7 x 10-6
|
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Applications for High Specific Stiffness
Graphite composites are ideally suited for applications where
high stiffness and low weight is required. Most metals used for
structural applications have very similar specific stiffness,
which is around 100 x 106. If an application demands high
stiffness and lightweight, graphite composites is the only material
of choice.
Examples are:
- Spacecraft structure
- Aircraft structure
- Drive shaft for trucks and high performance vehicles
- Machinery rollers
- Sail boat mast and boom
- Bicycle frame
- Machinery components that experience
high acceleration & require stiffness & precision
Applications for High Specific Strengths Graphite composites are widely used
for lightweight structures that need to carry extremely high loads.
Examples are:
- Motorcycle components (skid plates, rock guards)
- Fishing pole
- Golf club shaft
- Aircraft structure
- Satellite antenna structures
- Racecar chassis
Applications for Low CTE
Graphite fiber has a negative coefficient of thermal expansion,
which means when it is heated it will shrink. When the graphite
fibers are put into a resin matrix (positive CTE), the composite
can be tailored to have almost zero CTE. Graphite composites are
used for high precision and thermally stable applications.
Examples are:
- High precision antennas
- Scanning & imaging machines
- Precision optical devices
- Metrology equipment
Manufacturing Process
Graphite composite components are manufactured utilizing a molding process. The graphite
fibers can be woven into cloth, braided into tubes, or made into unidirectional tapes. The fibers
are next coated with resin. This fiber & resin mix can be partially cured then frozen to create a
pre-preg, or the fiber & resin mix can be used wet. The graphite fiber & resin mix is then placed
into a mold in layers. The number of layers and the orientation of the layers will depend on the
mechanical properties desired. The layers of graphite is then compacted and consolidated in the
mold by pressure from a press or from a vacuum bag. Depending on the resin system, the part can
be cured at room temperature or elevated temperature. Once the part is cured, the part is removed
from the mold, and it is ready for finishing operations such as trimming and drilling.
Design Information
Graphite composites are considered designer’s material, because the parts can be tailored to have
strength and or stiffness in the directions and locations that are necessary by strategically placing
materials and orienting fiber direction. Also the design and manufacturing flexibility that graphite
composites offers provide opportunities to consolidate parts and to incorporate many features into
the part to further reduce the total part price. Some general design guidelines are listed below:
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Material Thickness
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Typically
range from .040" to 1/2". Can use sandwich construction
to achieve lighter and stiffer parts.
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Corner Radius
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Recommend 1/8" or larger.
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Shape
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Will duplicate the shape of the mold. Can
be heavily contoured.
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Dimensional Tolerance
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+
.010" |
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Surface Finish
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Tool side can
be class A
Can be gel coated painted, or use any other surface coating
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Shrinkage
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.0005 in/in
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Electrical Properties
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Electrical
conductive |
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Fire Retarding
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Resins available in fire
retardant applications meeting various ASTM classes &
smoke generation requirements
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Corrosion
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Resins available for
corrosion applications, especially for hot brine, most
acids, caustics, & chlorine gases
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Tooling
Molds are used to define the shape of the fiberglass parts. The graphite composite part will pick
up all shapes and features of the molds; therefore the quality of the part is heavily influenced by
the quality of the mold. The molds can be either male or female. The female molds are the most
common and they will produce a part with a smooth exterior surface while a male mold will
produce a smooth interior surface. A matched mold (male and female) is required if the part is
consolidated using a press. The molds can be made with composite materials, metal filled epoxy,
or machined from aluminum or steel. The type of mold and materials used depends on the type of
part and the production quantity.
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